Basta usar um
OUTER APPLY primeiro a forçar um CAST :SELECT t.userid, r.z.value('@FieldName', 'nvarchar(MAX)')
FROM @t t
OUTER APPLY (SELECT CAST(t.xml as xml) as realxml) s
OUTER APPLY s.realxml.nodes('//Property') as r(z)
OUTER APPLY primeiro a forçar um CAST :SELECT t.userid, r.z.value('@FieldName', 'nvarchar(MAX)')
FROM @t t
OUTER APPLY (SELECT CAST(t.xml as xml) as realxml) s
OUTER APPLY s.realxml.nodes('//Property') as r(z)