Use uma subconsulta.
SELECT r.nID,
(SELECT r1.val FROM T1 r1 WHERE r.nID=r1.nID ORDER BY rand() LIMIT 1) AS 'val' FROM T1 r
GROUP BY r.nID
http://sqlfiddle.com/#!2/357b8/18
SELECT r.nID,
(SELECT r1.val FROM T1 r1 WHERE r.nID=r1.nID ORDER BY rand() LIMIT 1) AS 'val' FROM T1 r
GROUP BY r.nID
