Inquerir:
SQLFIDDLEExample
SELECT t1.*
FROM lms_attendance t1
WHERE t1.time = (SELECT MAX(t2.time)
FROM lms_attendance t2
WHERE t2.user = t1.user)
Resultado:
| ID | USER | TIME | IO |
--------------------------------
| 2 | 9 | 1370931664 | out |
| 3 | 6 | 1370932128 | out |
| 5 | 12 | 1370933037 | in |
Solução que vai funcionar sempre:
SQLFIDDLEExample
SELECT t1.*
FROM lms_attendance t1
WHERE t1.id = (SELECT t2.id
FROM lms_attendance t2
WHERE t2.user = t1.user
ORDER BY t2.id DESC
LIMIT 1)